MFRI HazMat Tech

Threshold Limit Value/ Time Weighted Average

Maximum airborne concentration maybe exposed to 8hrs a day 40hrs a week.

Permissible Exposure Limit

An OSHA term for the maximum concentration averaged over 8 hours, to which 95 percent of healthy adults can be repeatedly exposed for 8 hours per day, 40 hours per week.

Short Term Exposure Limit

STEL; legal limits established by OSHA to which workers can be exposed continuously for a short period of time without damage or injury; exposures at the STEL should not be for more than 15 minutes and not repeated more than four times per work day.

Threshold Limit Value/ Ceiling

This is the maximum concentration to which a health adult can be exposed without risk of injury, and the exposure to higher concentrations should not occur

Threshold Limit Value Skin

Indicates the concentration at which direct exposure or airborne contact with a material could result in possible and significant exposure by absorption through the skin, mucous membranes, and eyes.

Emergency Response Planning Guidelines ERPG-2

The maximum airborne concentration which is believed all individuals could be exposed for one hour.

Acute Emergency Exposure Guidelines

Cover five exposure periods, 10 min, 30 min, 1 hr, 4hr, 8 hrs

LD50

A chemical dose lethal to 50 percent of a test population

Lethal Concentration

Concentration of an inhaled substance that results in the death of a certain percentage of the test population; the lower the value the more toxic the substance; an inhalation exposure expressed in parts per million (ppm), milligrams per liter (mg/liter),

Curie

a unit of radioactivity equal to the amount of a radioactive isotope that decays at the rate of 37,000,000,000 disintegrations per second

Roetgen

unit used to measure nuclear radiation; it is equal to the amount of radiation that produces 2x10^9 ion pairs when it passes through 1 cm^3 of dray air

rem

(Roentgen Equivalent Man) the dosage of ionizing radiation that will cause the same amount of injury to human tissue as 1 roentgen of X-rays

RAD

Radiation absorbed dose

Incident Safety Officer

The command staff position assigned to monitor the scene for safety hazards or unsafe operations, enforce safety practices, and establish a safety plan.

Flammability

IDLH action is 10% of the lower explosive limit.

Non bulk packaged bags

Can be stiched, folded and glued, carry fertilizers, caustic powders, pesticides.

Carboys

Class 6,8
Up to 20 gal
Nonbulk to transport corrisive liquid

Bulk 1 ton containers

2 valves, 1 liquid 1 vapor

Supersacks

IBC, solid materials, miscllenous 500 to 5000 lbs

Rigid Containers

IBC 300 to 500 gal polyethylene tank inside a rigid steel frame

Pressure Tank Containers

4500 to 5500 intermodal with pressure capacity of 100 to 500 psi

Specialized tank tube modules

pressure ranges up 2400 psi or higher

MC306 DOT406

Low pressure cargo tank car, gasoline

MC307 DOT407

Low pressure chemical cargo

MC312 doT 412

Corrosive cargo tank

mc330

High pressure cargo tank truck

mc338

Cryogenic Liquid Cargo

markers on a pipeline

Pipeline content, operator, emer. Telephone

Placard 1

Explosives

Placard 2

Gas

Placard 3

Liquid

Placard 4

Flammable Solid

PLACARD 5

Oxidizer

Placard 6

Toxic and Infectious Substance

Placard 7

Radioactive

Placard 8

Corrosive Substances

Placard 9

Miscellaneous

Bill of lading

Highway

Waybill

Railroad

Marine

Dangerous goods manifest

Air

Airbill

Military Division 1

Mass detonation

Military Division 2

Explosion with fragment hazard

Military Division 3

Mass Fire Hazard

Military Division 4

Moderate Fire Hazard

Military Red Suit

Highly Toxic Chemical Agent

Military Yellow Suit

Harassing Agent

Military White Suit

White Phosphorus...

Cryogenic liquid

Liquids stored below -90C

Ionic Bonding

The electrostatic attraction between oppositely charged particles

Covalent Bonding

Force holding together elements that share an electron

Sublimation

The ability of a substance to change from the solid to the vapor phase without becoming a liquid

Miscibility

The ability of materials to dissolve into a uniform mixture

Vesicants

Blister agents, mustard gas

MSST maximum safe storage temperature

Maximum temp an organic peroxide can be maintained

CAMEO

Computer Assisted Management of Emergency Operations

MARPLOT

Mapping Applications for Response, Planning, and Local Operation

ALOHA

Aerial Locations of Hazardous Atmosphere Plooms

Chemical Test Strips

chlorine, PH, sulfides, oxidizers, flourides, nerve agents, cyanide, and arsenic

Runaway Cracking

Also known as a BLEVE

Score

Reduction in Thickness

Degradation

physical destruction or decomposition of a clothing material due to exposure to chemical

Penetration

flow of a hazardous chemical through closures seams, pinholes or other imperfections

Permeation

hazardous substance moves through a given material on the molecular level

Dilution

1) is not water reactive, 2) will not generate a toxic gas upon contact with water, 3) will not form any kind of solid or precipitate, 4) is totally water soluable