Chem Chap 17

Phosphorescence

the slow luminescence of substance previously exposed to light

Discovery of Radioactivity

Antoine-Henri Becquerel

Uranic rays

minerals produced rays, like x-rays but not phosphorescence. How Becquerel discovered radioactivity

Marie and Pierre Curie

discovered radium (green glow) and polonium (named for homeland). Renamed it radioactivity since not onyl uranic rays

Radioactivity

release of tiny high-energy particles. Particles ejected from nucleus

Properties of Radioactivity

can ionize matter. High energy rays. Rays Penetrate, can cause chemicals to glow

Alpha rays

charge of +2 and mass of 4. Helium nuclei

Beta rays

charge of -1 and no mass. They are electrons

Gamma Rays

form of light energy, higher than x-rays (0 and 0)

Positron

+1 and no mass. Mass number remains same and atomic number decreases by one when atom looses postiron

Penetrating Power

1) gamma 2) beta 3) alpha

Ionizing energy

1) alpha 2) beta 3) gamma

Parent nuclide

nuclues that is undergoing radio active decay

Daughter nuclide

new nuclei that are made

Beta emission

neutron changes into a proton and electron. Proton remains in nucleu and electron is emitted

Gamma Emission

1) electromagentic radiation- high energy, short wavelength photons 2) low ionizing power 3) high penetrating power

Alpha Emission

1) composed of 2 protons and 2 neutrons 2) high ionizing power 3) low penetrating power

Detecting Radioactivity

1) photographic film to detect presence 2) causes air to become ionized (electroscope and Geiger-Muller) 3) cause certain chemicals to give of flash of light (scintillation counter)

Electroscope

detects radiation by ability to penetrate the flask and ionzie air inside

Geiger-Muller

counts electrons generated when Ar gas atoms are ionzied

Scintillation Counter

counts number of flashes per minute

half-life

length of time it takes for half of a radioactive sample to decay

Decay Series

1) Count number of alpha and beta decays 2) From mass number subtract 4 for each alpha 3)from atomic number subtract 2 for each alpha and 1 for each Beta

Radon

Product of Uranium decay. Can contribute to cancers (lung). Energy efficient buildings with little air exchange with outdoors can build up in radon

Carbon dating

Half-life=5730 years.

Nuclear fission

Lead to Manhattan project b/c thought germany was developing weapons

Fissionable Isotopes

U-235, Pu-239, Pu-240

Nuclear power

Uses fission, 20% u.s. electricity, 70% in france. Heat boils water into steam. Stems turns turbine generating electricity

Fuel Rods

fissionable material stored here

Control Rods

made of neutron asborbing material. Neutrons needed to sustain the chain reaction. Rods placed in material to slow down ejected neutrons called moderators

Concerns Nuclear Power

1) Core melt-down 2) waste disposal 3) transporting waste 4) dealing with plants that are no longer safe

Nuclear Fusion

1) Combing of light nuclei to make heavier one 2) used by weapons and sun (fusion of hydrogen isotopes)

Nuclear weapons

start with small fission to triger the fusion (main bomb)

Biological Effects

1) Acut effects (rapidly dividing cells are sensitive) 2) increased cancer risk (DNA damage causes cell to act wierd) 3) Genetic defects (DNA damage- not observed in humans)

20-100

decreased white blood cell, possible cancer

100-400

radiation sickness; increased cancer risk

500+

death

Sources of Radiation

.3 rem per year from natural causes

Medical use

isotope scanning... organs absorb element... can measure by Geiger, Film, or Scintillation... want short half lifes and low ionizing power

iodine-131

locate tumors in thyroid

Selenium-75

look at pancreas

Gadolinium-153

to determine bone mineralization

Technetium 99m

used for cardiac perfusion.. half life of 6 hrs... very safe... m=metastable

PET Imaging

Positron Emission Tomography... positron annihilates electron to make two gamma rays...radiation in opposite directions

Radiotherapy

used to destroy tumors

Critical Mass

minimus amouint of fissionable isotope needed to sustain the chain reaction

Curies

measures activity of radioactive substance. I cure being 3.7*10^10

Roentgen

measures exposure. 1=2.58*10^-4 per kg of dry air at STP

Roentgen-equivalent man (Rem)

is the effective exposure (ionization) in human tissue. For most roentgen and rem are similar

Factors determining bio effects

1) more energy=larger effect 2)more penetration= more effect 3) more ionization=more effect 4)radioactive half-life 5) biological half-life 6) physical state of radioactive matter