Prentice Hall Chemistry Chapter 19: Acids, Bases, and Salts

Tastes sour

Acid

Changes the color of an acid-base indicator (acid, base, or both)

Both

Can be strong or weak electrolytes in aqueous solution

Acid

In drinks, citrus, pop, etc.

Acid

This acid is associated with protein

amino acid

Used in fragrances and flavors

Acid

Type of acid in DNA and RNA

nucleic acid

Gastric acid is also known as

HCl

Cleaning agents, antacids

Base

Example: milk of magnesia

Base

React with acids

Base

Used in making soaps, detergents, etc

Base

Used in chemical reactions (making polymers, drugs, etc)

Base

React with metals to produce hydrogen gas

Acid

Used as preservative (foods)

Acid

Slippery feel

Acid

Bitter taste

Base

Used as antacids (neutralization reaction)

Base

Three types of acids and bases: (hint: in alphabetical order)

Arrhenius, Bronsted-Lowry, Lewis

Said that acids are hydrogen-containing compounds that ionize to yield hydrogen ions (H+) in aqueous solutions.

Arrhenius

Said that bases are compounds that ionize to yield hydroxide ions (OH-) in aqueous solution

Arrhenius

Acids that contain one ionizable hydrogen

Monoprotic

Acids that contain two ionizable hydrogens

Diprotic

Acids that contain three ionizable hydrogens

Triprotic

Example of monoprotic acids (formula)

HNO3

Example of diprotic acid (formula)

H?SO?

Example of triprotic acids (formula)

H?PO?

Example of monoprotic acid (name)

nitric acid

Example of diprotic acid (name)

sulfuric acid

Example of triprotic acid (name)

phosphoric acid

True or False: All compounds that contain hydrogen are acids

False

Formula for potassium hydroxide

KOH

Formula for sodium hydroxide

NaOH

Formula for Calcium hydroxide

Ca(OH)?

Formula for Magnesium hydroxide

Mg(OH)?

Who defines an acid as a hydrogen-ion donor

Bronsted-Lowry

Who defines a base as a hydrogen-ion acceptor

Bronsted-Lowry

According to Bronsted-Lowry, is ammonia a base or acid?

Base

Vocabulary: The particle formed when a base gains a hydrogen ion

Conjugate acid

The particle that remains when an acid has donated a hydrogen ion

Conjugate base

Consists of two substances related by the loss or gain of a single hydrogen ion.

Conjugate acid-base pair

A water molecule that gains a hydrogen ion becomes a positively charged _________

hydronium ion

The conjugate base of the acid HCl (what ion?)

Chloride ion

Conjugate acid of the base water (what ion?)

hydronium ion

Conjugate base of HCl (formula)

Cl-

Conjugate acid of Cl-

HCl

Conjugate base of H?SO?

HSO??

Conjugate acid of HSO??

H2SO4

Conjugate base of H?O

OH-

Conjugate acid of OH-

H?O

Conjugate base of NH??

NH?

Conjugate acid of CH?COO-

CH?COOH

Conjugate base of CH?COOH

CH3COO-

A substance can act as both an acid and a base is said to be ___________

amphoteric

Example of amphoteric substance (common name)

water

Who proposed that an acid accepts a pair of electrons during a reaction?

Lewis

Who proposed an base donates a pair of electrons during a reaction?

Lewis

According to Lewis, an acid (accepts/donates) a pair of electrons during a reaction

accepts

According to Lewis, an base (accepts/donates) a pair of electrons during a reaction

donates

According to Lewis, a substance can accept or donate a pair of electrons to form a ____ bond

covalent

According to Arrhenius, an acid is an H?________

producer

According to Arrhenius, a base is an OH- _____

producer

According to Bronsted-Lowry, an acid is an H?______

donor

According to Bronsted-Lowry, a base is an H+ _____

acceptor

According to Lewis, an acid is an electron-pair_____

acceptor

According to Lewis, a base is an electron pair _______

donor

The reaction in which water molecules produce ions is called

self-ionization

Any aqueous solution in which [H+] and [OH-] are equal is described as a _______ ________

neutral solution

In any aqueous solution, when [H+] increases, [OH-] _____

decreases

When [H+] ______, [OH-] increases

decreases

For aqueous solutions, the product of the hydrogen-ion concentration and the hydroxide-ion concentration equals =

1.0 x 10?�?

The product of the concentrations of the hydrogen ions and hydroxide ions in water is called the (long name)

ion-product constant for water

The ion-product constant for water

Kw

True or false: not all solution are neutral

true

Type of solution in which [H+] is greater than [OH-]

acidic

The [H+] of an acidic solution is greater than 1 x 10^? M

-7

Type of solution in which [H+] is less than [OH-]

basic

The [H+] of a basic solution is less than 1 x 10^?M

-7

Basic solutions are also known as ______ solutions

alkaline

The pH scale ranges from __ to __

0, 14

A pH of 0 is strongly

acidic

A pH of 14 is strongly

basic

The __ of a solution is the negative logarithm of the hydrogen-ion concentration

pH

-log[H+] =

pH

Neutral solutions have a pH of

7

Acidic solutions have a pH lower than

7

Basic solutions have a pH ____ than

higher

The ____ of a solution equals the negative logarithm of the hydroxide-ion concentration

pOH

-log[OH-] = ___

pOH

A neutral solution has a pOH of

7

A solution with a pOH < 7

basic

A solution with a pOH >7

acidic

pH + pOH =

14

pH = 14 - ___

pOH

____ = 14 - pH

pOH

For precise and continuous measurements, what sort of device would you use to measure the pH of a substance?

meter

An acid or a base that undergoes dissociation in a known pH range

indicator

A valuable tool for measuring pH because its acid form and base have different colors in solution

indicator

Acids are classified as strong or weak depending on the degree to which they ___ in water

ionize

___ acids are completely ionized in aqueous solutions

strong

___ acids ionize only slightly in aqueous solution

weak

Acid dissociation constant

Ka

Ka is what constant? _____ ___________

Acid dissociation

Weak acids have ____ Ka values

small

Strong acids have ___ Ka values

large

___ bases dissociate completely into metal ions and hydroxide ions in aqueous solution

strong

____ bases react with water to form the hydroxide ion and the conjugate acid of the base

weak

Base dissociation constant

Kb

Kb is what constant? ____ _________

base dissociation

Reactions in which an acid and a base react in an aqueous solution to produce a salt and water are called

neutralization reactions

In general, the reaction of an acid with a base produces and ______

salt

Compounds consisting of an anion from an acid and a cation from a base

salt

When an acid and base are mixed, the ____________ _________ is when the number of moles of hydrogen ions equals the number of moles of hydroxide ions

equivalence point

The number of moles of hydrogen ions provided by an acid are equivalent to the number of _________ ions provided by the base

hydroxide

You can determine the concentration of acid (or base) in a solution by performing a __________________ reaction

neutralization

The process of adding a known amount of solution of known concentration to determine the concentration of another solution is called

titration

The solution of known concentration is called the

standard solution

The point at which the indicator changes color is the ______ _______ of the titration

end point

The point of neutralization is the _____ point of the titration

end

A salt consists of an ____ of an acid and a ____ of a base

anion, cation

True or false: all salts are neutral

false

In this process, the cations or anions of a dissociated salt remove hydrogen ions from or donate hydrogen ions to water

salt hydrolysis

Salts that produce acidic solutions contain ________ ions that release protons to water

positive

Salts that produce basic solutions contain (negative/positive) ions that attract (neutrons, protons, electrons)

negative, protons

Strong acid + Strong base = ______ solution

neutral

Strong acid + Weak base = _________ solution

acidic

Weak acid + Strong base = ________ solution

basic

______ is a solution in which the pH remains relatively constant when small amounts of acid or base are added

buffer

A buffer is a solution of a ____ acid and on of its salts, or a solution of a ____ base and one of its salts

weak, weak

True or false: A buffer solution is better able to resist drastic changes in pH than is purse water

true

The amount of acid or base that can be added to a puffer solution before a significant change in pH occurs

buffer capacity

A base is a source of ______________ ions

hydroxide

# of buffer systems crucial in maintaining human blood pH within a narrow range (pH 7.35-7.45)

2

Name the buffer system involving etha--

ethanoic acid-ethanoate ion

Name the buffer system involving dihy--

dihydrogen phosphate ion-hydrogenphosphate ion,

Name the buffer system involving ca--

carbonic acid-hydrogen carbonate ion

Name the buffer system involving amm-

ammonium ion-ammonia

Which of these is not crucial to human blood? (A) Ammonium ion-ammonia, (B) ethanoic acid-ethanoate ion, (C) Dihydrogen phosphate-monohydrogen phosphate

B

What type of type of salt produces an acidic solution? One that contains ________ ____ _____ _______ ____________ _____ __________

positive ions that release protons to water

What type of salt produces a basic solution? One that contains ________ ____ _____ _______ ____________ _____ __________

negative ions that attract protons from water