Modern Chemistry Chapter 11

Ideal Gas Law

PV=nRT

P

Pressure

V

Volume

n

Moles

R

Constant

T

Temperature

Boyle's Law

The volume of a fixed mass of gas varies inversely with the pressure at constant temperature PV=K P1V1 = P2V2

STP

0 degrees C and 1 atm

Charles's Law

The volume of a fixed mass of gas at constant pressure varies directly with Kelvin temperature V=kT V1 / T1 = V2 / T2

Gay-Lussac's Law

The pressure of a fixed mass of gas at constant volume varies directly with the Kelvin temperature P=kT P1 / T1 = P2 / T2

Combined Gas Law

expresses the relationship between pressure, volume, and temperature of a fixed amount of gas PV / T = k P1V1T2 = P2T2T1

Gay-Lussac's Law of Combining Volumes

at constant temperature and pressure, the volumes of gaseous reactants and products can be expressed as ratios of small whole numbers

Avogadro's Law

equal volumes of gases at the same temperature and pressure contain equal numbers of molecules V = kn V-volume k-constant n-amount of gas in moles

Standard Molar Volume of a Gas

the volume occupied by one mole of a gas at STP =22.414 L

Grahm's Law of Effusion

the rates of effustion of gases at the same temperature and pressure are inversely proportional to the square roots of their molar masses Rate of effusion of A / B = ?Mb / ?Ma

Kinetic-Molecular Theory

particles of matter are always in motion

Ideal Gas

a hypothetical gas that perfectly fits all the assumptions of the kinetic-molecular theory

Elastic Collision

a collision in which there is no net loss of total kinetic energy

diffusion

spontaneous mixing of the particles of two substances caused by their random motion

effusion

a process by which gas particles pass though a tiny opening

Real Gas

a gas that does not behave completely according to the assumptions of the kinetic-molecular theory

Millimeters of Mercury

mmHg 760 mmHg

atmosphere pressure

1 atm

Kilopascal

101.325kPa

Dalton's law of partial pressures

the total pressure of a gas mixture is the sum of the partial pressures of the component gases

partial pressure

the pressure of each gas in a mixture