Organic Chemistry Functional Groups

alkanes

No functional group

alkenes

C-C pi bond

alkynes

two C-C pi bonds

aromatics

three C-c pi bonds

phenols

hydroxyl group on benzene

alkyl halides

C-X

alcohols

hydroxyl group

thiols

sulfhydryl group

ethers

O between two alkyl groups

epoxides

ether in a 3 membered ring

sulfide (or thioether)

S between two alkyl groups

ketones

carbonyl group (C=O)

aldehydes

carbonyl group (C=O)

carboxylic acids

carboxyl group (acidic proton and carbonyl group)

esters

carboalkoxy group

amides

carboxamide group

acyl halide (or acid halide)

halocarbonyl group

acid anhydride

anhydride group

amines

amino groups

ammonium ions

ammonium group

boranes

C-B sigma bond and an empty B 2p AO

nitroalkanes

nitro group

nitriles

nitrile group (two C-N pi bonds)

imines

imino group (C-N pi bond)

enamines

C-C pi bond attached to N

alkanes

No functional group

alkenes

C-C pi bond

alkynes

two C-C pi bonds

aromatics

three C-c pi bonds

phenols

hydroxyl group on benzene

alkyl halides

C-X

alcohols

hydroxyl group

thiols

sulfhydryl group

ethers

O between two alkyl groups

epoxides

ether in a 3 membered ring

sulfide (or thioether)

S between two alkyl groups

ketones

carbonyl group (C=O)

aldehydes

carbonyl group (C=O)

carboxylic acids

carboxyl group (acidic proton and carbonyl group)

esters

carboalkoxy group

amides

carboxamide group

acyl halide (or acid halide)

halocarbonyl group

acid anhydride

anhydride group

amines

amino groups

ammonium ions

ammonium group

boranes

C-B sigma bond and an empty B 2p AO

nitroalkanes

nitro group

nitriles

nitrile group (two C-N pi bonds)

imines

imino group (C-N pi bond)

enamines

C-C pi bond attached to N