Chemistry paper 2

Products of complete combustion

Co2 + water

Test for alkenes

Turns bromine water orange -> colourless

What type of reaction is cracking

Thermal decomposition

Condition for addition reaction of alkene and hydrogen

60 degrees + nickel catalyst

What is a pure substance

A single element or compound, not mixed with any mother substance
(Has specific and fixed Melting + boiling point)

What is a formulation

A mixture that has been designed as a useful product with definite proportions

How to test for hydrogen

Metal + acid
Lit splint = squeaky pop

How to test for oxygen

D�composition of hydrogen peroxide with a manganese oxide catalyst
Glowing splint relights

How to test for CO2

Calcium carbonate + hydrochloric acid -> calcium chloride + water + co2
Turns limewater Cloudy

How to test for chlorine

Hydrochloric acid + moistened potassium manganate crystals
Bleaches damp blue litmus paper

What do impurities do?

Lower the melting point
Raise the boiling pint

In chromatography, what is the mobile phase

The solvent - moves through stationary phase, carrying compounds with it

Equation for chromatography

Rf = distance moves by substance / distance moved by solvent

Copper (II) ppt colour and equation

Blue port Cu(oH)2

Iron (II) ppt colour and equation

Green Fe(OH)2

Iron (III) ppt colour and equation

Brown Fe(OH)2

Which ion redissolvws in excess out of aluminium, magnesium and calcium

Aluminium

Lithium flame colour

Crimson red

Calcium flame colour

Brick red

Potassium flame colour

Lilac

Copper flame colour

Green

Sodium flame coulour

Yellow

How to test for sulfates

Add sulfate solution to HCL and barium chloride
White ppt, barium sulfate BaSO4 is produced

Test for carbonates

Add dilute acid to carbonate
CO2 gas is produced which turns limewater cloudy

Testing for halides

Add nitric acid and silver nitrate to halide solution
Ppt of silver balise forms of present

Colour of iodide ppt

Yellow

Colour of Bromide ppt

Green

Colour of chloride ppt

White

What did Earth's early atmosphere contain?

CO2, water vapour, nitrogen and traces of methane and ammonia

How can sulfur impurities be removed

By reacting fuel with calcium oxide

Stages of sewage treatment

Metal screening -> primary treatment (sedimentation) -> secondary treatment (anaerobic and aerobic) -> final treatment (sterilisation)

What happens during the primary treatment of sewage waste

Produces Sewage sludge and effluent + separates them

What happens during the secondary treatment of sewage waste

Aerobic respiration - removes organic matter + harmful organisms from effluent
Anaerobic respiration - digests sewage sludge

What are the two methods of extracting copper from copper ore

Add sulfuric acid to produce copper sulfate solution - extract during electrolysis or displacement
Smelting - copper heated to high temp in furnace - produces injure copper - used as + electrode in electrolysis

How can copper be extracted from low grade ores

Phytomining
Bioleaching

What does a LCA do

Asses environmental impact of products, processes or services

3 things that the RRR campaign aims to reduce

Amount of waste we produce
Amount of finite resources we use
Amount of energy we use

What is sustainable development?

An approach to development that takes account the needs of present society without damaging the lives of future generations

Potable water

Water that is safe to drink
Contains low levels of dissolved salts/ minerals
Free of microbes

Stages in water treatment

Filter screens -> filter beds -> Remove microbes -> check PH

What is the prices of converting salty water to potable water called

Desalination

Two methods of desalination

Distillation/ flash distillation (boiling water under reduced pressure)
Reverse osmosis

What is reverse osmosis

Uses membranes to separate water from dissolved salts

What is rusting?

The corrosion of iron

What is corrosion?

Destruction of materials by chemical reactions with substances in the environment

Conditions of rusting

Water + Oxygen + iron

What accelerates rusting

Salt

What does iron become when rusted

Hydrated iron (III) oxide
Fe2O3

How to prevent corrosion - barrier method (4)

Paint
Grease/Oil
Plastic
Less reactive metal

What is sacrificial protection

Coating iron with a more reactive metal
Iron is galvanised by zinc

Why is a more reactive metal used in sacrificial protection

It is more likely to lose electrons and become oxidised therefore, water and oxygen reacts with zinc rather than iron
Zinc = stronger reducing agent

Properties of Bronze

Tin + copper
Tough + resistant to corrosion

Properties of Brass

Copper + Zinc
Harder than copper
Can be worked into intricate shapes

Why is aluminium used in a lot of alloys

Low density
Strong but lightweight

What is steel an alloy of?

Iron

High carbon steel

1-5%
Strong and hard
Brittle

Low Carbon Steel

<1%
Softer
Less brittle
Easily shaped

Nickel - steel alloys

Resistant to stretching forces
Strong

Stainless steek

Chromium and Nickel
Hard and strong
Resistant to corrosion

What do properties of a polymer depend on (2)

Monomer used
Reaction conditions

Low Density Polyethene

High pressure + trace of oxygen
Branched chains

High Density Polyethene

Catalyst, 50c and slightly higher pressure
Straight chains
Harder

Thermosoftening polymers

Melt easily
Polymer chains easy to separate
Can be remoulded

Thermosetting Polymers

Do not melt when heated
String covalent bonds forming cross links

What does all glass contain

Silicon Dioxide (sand) SiO2

SodaLime glass (3)

Sand
Sodium carbonate
Limestone

Borosilicate glass

Sand
Boron trioxide

What is a composite

Mixture of substances that together provide properties suitable for a particular use

What is a composite made from (2)

- 1 material acting as a binder for the other
- other material provides a desirable property
Process called reinforcement

How is glass made (3)

Raw materials heated to 1,500c to make chemicals melt + react to form molten glass
Glass turns into solid as it cools
Particles freeze in place to form irregular pattern

Properties of clay ceramics (3)

Hard but brittle
Resistant to chemical attack
Electrical insulator

Plywood

Thin sheets of wood glued together
Grain in successive layers at right angles to eachother - prevents splitting

MDF

Made from woods chips, shavings or sawdust compressed and bound using a polymer resin
Can be cut into intricate shapes

Reinforced concrete

Set around steel rods
Resistant to bending

Fibre glass

Composite of glass + polymer
Tough
Flexible
Waterproof
Low-density

Concrete

Cement, gravel, sand and water

Why can't plants take in nitrogen gas

It's insoluble in water + most plants can only take in a soluble form of nitrogen

Raw materials in Haber Process

Nitrogen for air
Hydrogen ( from methane + steam)

What happens to the nitrogen and hydrogen in the haber process

They are purified, passed over an iron catalyst at 450c + high pressure

Equation for haber process

Nitrogen + hydrogen -> Ammonia
N2 3H2 <- 2NH3

What are the reaction conditions for the Haber process

200 atm
Iron catalyst
450c

Ammonium nitrate reaction

Ammonia + nitric acid -> ammonium nitrate
NH3. HNO3. NH3NO3

How is nitrogen obtained for haber process

Separated from air via factional distillation of liquid air

How is hydrogen obtained for haber process

Methane + Steam = carbon monoxide + hydrogen
Requiers High temp

In the Haber process which reaction is exothermique?

Forward reaction

Ammonium phosphate reaction

Ammonia + phosphoric acid -> ammonium phosphate
3NH3. H3PO4. (NH4)3PO4

Ammonium sulfate reaction

Ammonia + sulfuric acid -> ammonium sulfate
2NH3. H2SO4. (NH4)2SO4

What 3 macronutrients do plants need

Phosphorus - promote strong roots and fruit development
Potassium - healthy growth
Nitrogen - helps make leaves green

What are NPK fertilisers

Formulations of compounds of Phospohirus, nitrogen and potassium

Why can't phosphorus be used directly on soil

It's insoluble in water

3 ways of using phosphorus

1)Phosphate rock + nitric acid -> phosphoric acid + calcium nitrate
Phosphoric acid + ammonia - ammonium phosphate
2)phosphate rock + sulfuric acid -> single superphosphate (calcium phosphate + calcium sulfate)
3)phosphate rock + phosphoric acid -> triple

What two potassium salts are used to make fertilisers and why

Potassium chloride and potassium sulfate
Soluble and can be used directly

Products of complete combustion

Co2 + water

Test for alkenes

Turns bromine water orange -> colourless

What type of reaction is cracking

Thermal decomposition

Condition for addition reaction of alkene and hydrogen

60 degrees + nickel catalyst

What is a pure substance

A single element or compound, not mixed with any mother substance
(Has specific and fixed Melting + boiling point)

What is a formulation

A mixture that has been designed as a useful product with definite proportions

How to test for hydrogen

Metal + acid
Lit splint = squeaky pop

How to test for oxygen

D�composition of hydrogen peroxide with a manganese oxide catalyst
Glowing splint relights

How to test for CO2

Calcium carbonate + hydrochloric acid -> calcium chloride + water + co2
Turns limewater Cloudy

How to test for chlorine

Hydrochloric acid + moistened potassium manganate crystals
Bleaches damp blue litmus paper

What do impurities do?

Lower the melting point
Raise the boiling pint

In chromatography, what is the mobile phase

The solvent - moves through stationary phase, carrying compounds with it

Equation for chromatography

Rf = distance moves by substance / distance moved by solvent

Copper (II) ppt colour and equation

Blue port Cu(oH)2

Iron (II) ppt colour and equation

Green Fe(OH)2

Iron (III) ppt colour and equation

Brown Fe(OH)2

Which ion redissolvws in excess out of aluminium, magnesium and calcium

Aluminium

Lithium flame colour

Crimson red

Calcium flame colour

Brick red

Potassium flame colour

Lilac

Copper flame colour

Green

Sodium flame coulour

Yellow

How to test for sulfates

Add sulfate solution to HCL and barium chloride
White ppt, barium sulfate BaSO4 is produced

Test for carbonates

Add dilute acid to carbonate
CO2 gas is produced which turns limewater cloudy

Testing for halides

Add nitric acid and silver nitrate to halide solution
Ppt of silver balise forms of present

Colour of iodide ppt

Yellow

Colour of Bromide ppt

Green

Colour of chloride ppt

White

What did Earth's early atmosphere contain?

CO2, water vapour, nitrogen and traces of methane and ammonia

How can sulfur impurities be removed

By reacting fuel with calcium oxide

Stages of sewage treatment

Metal screening -> primary treatment (sedimentation) -> secondary treatment (anaerobic and aerobic) -> final treatment (sterilisation)

What happens during the primary treatment of sewage waste

Produces Sewage sludge and effluent + separates them

What happens during the secondary treatment of sewage waste

Aerobic respiration - removes organic matter + harmful organisms from effluent
Anaerobic respiration - digests sewage sludge

What are the two methods of extracting copper from copper ore

Add sulfuric acid to produce copper sulfate solution - extract during electrolysis or displacement
Smelting - copper heated to high temp in furnace - produces injure copper - used as + electrode in electrolysis

How can copper be extracted from low grade ores

Phytomining
Bioleaching

What does a LCA do

Asses environmental impact of products, processes or services

3 things that the RRR campaign aims to reduce

Amount of waste we produce
Amount of finite resources we use
Amount of energy we use

What is sustainable development?

An approach to development that takes account the needs of present society without damaging the lives of future generations

Potable water

Water that is safe to drink
Contains low levels of dissolved salts/ minerals
Free of microbes

Stages in water treatment

Filter screens -> filter beds -> Remove microbes -> check PH

What is the prices of converting salty water to potable water called

Desalination

Two methods of desalination

Distillation/ flash distillation (boiling water under reduced pressure)
Reverse osmosis

What is reverse osmosis

Uses membranes to separate water from dissolved salts

What is rusting?

The corrosion of iron

What is corrosion?

Destruction of materials by chemical reactions with substances in the environment

Conditions of rusting

Water + Oxygen + iron

What accelerates rusting

Salt

What does iron become when rusted

Hydrated iron (III) oxide
Fe2O3

How to prevent corrosion - barrier method (4)

Paint
Grease/Oil
Plastic
Less reactive metal

What is sacrificial protection

Coating iron with a more reactive metal
Iron is galvanised by zinc

Why is a more reactive metal used in sacrificial protection

It is more likely to lose electrons and become oxidised therefore, water and oxygen reacts with zinc rather than iron
Zinc = stronger reducing agent

Properties of Bronze

Tin + copper
Tough + resistant to corrosion

Properties of Brass

Copper + Zinc
Harder than copper
Can be worked into intricate shapes

Why is aluminium used in a lot of alloys

Low density
Strong but lightweight

What is steel an alloy of?

Iron

High carbon steel

1-5%
Strong and hard
Brittle

Low Carbon Steel

<1%
Softer
Less brittle
Easily shaped

Nickel - steel alloys

Resistant to stretching forces
Strong

Stainless steek

Chromium and Nickel
Hard and strong
Resistant to corrosion

What do properties of a polymer depend on (2)

Monomer used
Reaction conditions

Low Density Polyethene

High pressure + trace of oxygen
Branched chains

High Density Polyethene

Catalyst, 50c and slightly higher pressure
Straight chains
Harder

Thermosoftening polymers

Melt easily
Polymer chains easy to separate
Can be remoulded

Thermosetting Polymers

Do not melt when heated
String covalent bonds forming cross links

What does all glass contain

Silicon Dioxide (sand) SiO2

SodaLime glass (3)

Sand
Sodium carbonate
Limestone

Borosilicate glass

Sand
Boron trioxide

What is a composite

Mixture of substances that together provide properties suitable for a particular use

What is a composite made from (2)

- 1 material acting as a binder for the other
- other material provides a desirable property
Process called reinforcement

How is glass made (3)

Raw materials heated to 1,500c to make chemicals melt + react to form molten glass
Glass turns into solid as it cools
Particles freeze in place to form irregular pattern

Properties of clay ceramics (3)

Hard but brittle
Resistant to chemical attack
Electrical insulator

Plywood

Thin sheets of wood glued together
Grain in successive layers at right angles to eachother - prevents splitting

MDF

Made from woods chips, shavings or sawdust compressed and bound using a polymer resin
Can be cut into intricate shapes

Reinforced concrete

Set around steel rods
Resistant to bending

Fibre glass

Composite of glass + polymer
Tough
Flexible
Waterproof
Low-density

Concrete

Cement, gravel, sand and water

Why can't plants take in nitrogen gas

It's insoluble in water + most plants can only take in a soluble form of nitrogen

Raw materials in Haber Process

Nitrogen for air
Hydrogen ( from methane + steam)

What happens to the nitrogen and hydrogen in the haber process

They are purified, passed over an iron catalyst at 450c + high pressure

Equation for haber process

Nitrogen + hydrogen -> Ammonia
N2 3H2 <- 2NH3

What are the reaction conditions for the Haber process

200 atm
Iron catalyst
450c

Ammonium nitrate reaction

Ammonia + nitric acid -> ammonium nitrate
NH3. HNO3. NH3NO3

How is nitrogen obtained for haber process

Separated from air via factional distillation of liquid air

How is hydrogen obtained for haber process

Methane + Steam = carbon monoxide + hydrogen
Requiers High temp

In the Haber process which reaction is exothermique?

Forward reaction

Ammonium phosphate reaction

Ammonia + phosphoric acid -> ammonium phosphate
3NH3. H3PO4. (NH4)3PO4

Ammonium sulfate reaction

Ammonia + sulfuric acid -> ammonium sulfate
2NH3. H2SO4. (NH4)2SO4

What 3 macronutrients do plants need

Phosphorus - promote strong roots and fruit development
Potassium - healthy growth
Nitrogen - helps make leaves green

What are NPK fertilisers

Formulations of compounds of Phospohirus, nitrogen and potassium

Why can't phosphorus be used directly on soil

It's insoluble in water

3 ways of using phosphorus

1)Phosphate rock + nitric acid -> phosphoric acid + calcium nitrate
Phosphoric acid + ammonia - ammonium phosphate
2)phosphate rock + sulfuric acid -> single superphosphate (calcium phosphate + calcium sulfate)
3)phosphate rock + phosphoric acid -> triple

What two potassium salts are used to make fertilisers and why

Potassium chloride and potassium sulfate
Soluble and can be used directly