MOD 1 PHARM CHEM

Plasma

Hot ionized gas

Solid

?? Shape
?? Volume
Strongest IFA

Liquid

??Shape
??Volume
Strong IFA

Gas

??Shape
??Volume
Weakest IFA

Melting / Fusion

Solid to Liquid

Evaporation

Liquid to Gas

Condensation

Gas to Liquid

Freezing

Liquid to Solid

Sublimation

Solid to Gas

Deposition

Gas to Solid

Heat of Fusion

The energy required to change a gram of a subs. from the solid to liquid state without changing its temperature

Heat of Vaporization

The energy required to change a gram of liquid to gas state at the boiling point

7

Oxidation State of
Mn in KMnO4

6

Oxidation State of
Cr in K2Cr2O7

KMnO4

Mineral chameleon

KMnO4

Titrant in Permanganometry
f=5

Oxalic Acid

Use to remove stain of KMnO4

Combination

A + B = AB

Synthesis

Other name of combination

Analysis

Other name of decomposition

Decomposition

AB = A + B

Single Displacement

A + BC = AC + B

Metathesis

Aka double displacement

Double displacement

AB + CD = AC + BD

Burning

Aka combustion

Combustion

CxHy + O2 = CO2 + H2O

CO2

Complete combustion product

CO

Incomplete combustion product

Cupric sulfate

Component of Fehling's reagent

Blue vitriol

Aka cupric sulfate

Citric Acid and Tartaric Acid

Acidulants in effervescent formulation (2)

NaHCO3

Carbonating agent on effervescent formulation

Alkali + Silicon

How to make glass

Oxidation

Chem. Rxn involved in burning of woods

Nuclear change

Change in the nucleus of the atin

Nuclear Fusion

When to nuclei unite to form on nucleus

Nuclear Fission

One nucleus splits up to form two nuclei

Cr-51

Radio pharmaceutical
Volume of RBC and blood volume

Sodium Iodide I-131

Radio pharmaceutical
Thyroid function

Tc 99m human albumin

Radio pharmaceutical
Cardiac and peripheral blood pool imaging

Tc 99m human albumin macroaggregates

Radio pharmaceutical
Lung perfusion

Tc 99m DTPA

Radio pharmaceutical
Renal imaging

Tc 99m etidronate

Radio pharmaceutical
Bone imaging

Goldstein

Discovered proton

Chadwick

Discovered neutron

Thomson

Discovered electron

Proton and Neutron

They are called nucleons

Isotopes

Diff elements
Same # of protons

Isotones

Diff elements
Same # of neutrons

Isobars

Diff elements
Same atomic mass / mass number / atomic weight

Democritus

Said that the atom is indivisible

John Dalton

Billiard ball model

JJ Thomson

Plum pudding model

Raisin bread model

Aka plum pudding model

Ernest Rutherford

Gold Foil Exp.

Neils Bohr

Planetary Model

Schrodinger

Quantum mechanic model

Principal

Determined the SIZE of the atom

Principal

Quantum number symbol
n

Azimuthal

Determines the SHAPE of the orbitals

Azimuthal

Quantum number symbol
l

Magnetic

Determines the ORIENTATION in space

Magnetic

Quantum number symbol
ml

Spin

Determines the ROTATION of electron

Spin

Quantum number symbol
ms

Aufbau's

Lower orbitals should be filled up first

Pauli's

No two electrons can have the same set of quantum number

Heisenberg's

Cannot predict the position and the movement of electron simultaneously

Hund's

Single before pairing up

sp3

Have 4 coordination number

sp2

Have 3 coordination number

sp

Have 2 coordination number

Nihonium

Ununtrium

Nihonium

Element 113

Nihonium

Nh

Moscovium

Ununpentium

Moscovium

Element 115

Moscovium

Mc

Tennessine

Ununseptium

Tennessine

Element 117

Oganesson

Ununoctium

Oganesson

118

Si Ge Po Sb As Te

Metalloids

Al

Most abundant metal

Li

Treatment of mania

K

Metal with diuretic action

Au

Metal to treat arthritis

Fe Co Ni
Ru Rd Pd
Os Ir Pt

Triad Elements

Al and Ca

Ampotheric metals

Family A

Aka Representative elements

H

Most reactive element

Be

Most toxic

Mg

Present in chlorophyll

Mg

Present in GRIGNARD's rgt

Ca

Causes
Coagulation
Contraction
Release of NeuroTrans
Teeth and Bones

Ra

Discovered by Curie

B

?? the coefficient of expansion of glass

Al

Astringent
Taken orally - constipation
Ampotheric

C

King of all elements

Si

Manufacture of glass

Pb

Can affect the HEME syn.

EDTA

Pb toxicity antidote

Pb

Toxic element : plubism

N

Black container

P

St. Elmo's Fire

As

Choice of professional poisoner

As

Aka lewisite metal

BAL

Lewisite metal poisoning antidote

Bi

Aka beautiful meadow

Bi

Use to inh. the growth of H. pylori

O

Aka empyreal air

O

Green container

O

Most abundant element

O

Most important element

S

Aka shulbari

S

Aka brimstone

F

Most electronegative element

Cl

Green gas

Br

Brown liq.

I

Oldest known germicide

Astatine

Rarest element

Family B

Transition elements

Zn

Present in insulin

Zn

Rinman's Green Test

Hg

Messenger of the gods

Hg

Minamata dse

Methyl Hg

Most toxic form of Hg

Cd

Itai-itai dse

Au

King of all metals

Au

Most malleable

Au

Most ductile

Au

Best conductor of electricity

Ag

2nd most malleable

Ag

2nd most ductile

Ag

2nd best conductor of electricity

Cu

Only reddish metal

Cu

3rd most malleable

Cu

3rd most ductile

Cu

3rd best conductor of electricity

W

Aka wolfram

Ta

Surgical repair of bones, tissues and nerves

Ta

Not affected by body fluids

Tc

First artificial element

Fe

Synergistic with Vit. C

Fe

Imp. component of HEME and cytochrome

Os

Densest element

Co

Present in cyanocobalamin (B12)

Ni

Present in fake jewelries

Calcium sulfate dihydrate

Gypsum

Calcium sulfate hemmihydrate

Plaster of Paris

MgSO4

Epsom Salt

NaNO3

Chile Salt Peter

KNO3

Salt Peter

Na2CO3 10H2O

Washing soda

NaCO3

Soda ash

NaHCO3

Baking Soda

NaHCO3

Most common urinary alkalinizer

NaHCO3

Antidote for ASA tox

NaHCO3

Tx for metabolic acidosis

NaSO4

Glauber's Salt

NaK C4H4O6

Rochelle Salt

Pb subacetate

Goulard's Extract

Pb acetate

Sugar of Pb

Boric acid

Aka sal sativum

Boric acid

Eye wash
Weak germicide
Not antibiotic

NaH2PO4

Fleet Enema

NaOH

Caustic soda

Na hypochlorite

Dakin's solution

NaCl

Table salt

NaCl

Soler salt

NaCl

Antidote for Ag tox

KC4H5O6

Cream of Tartar

KOH

Caustic potash

Cupric sulfate

Blue vitriol

FeSO4

Green Vitriol

ZnSO4

White vitriol

H2SO4

Oil of Vitriol

AgNO3

Lunar Caustic

Mg(OH)2

Milk of Magnesia

HgCl

Calomel

HgCl2

Corrosive sublimate

Ammoniated Hg

White precipitate

Ammonium silicate

China clay

Ammonium silicate

KAOLIN

Nitrous oxide

Laughing gas

Ferric ferrocyanide

Prussian blue

Ferrous ferricyanide

Turnbull's blue

Magnesium silicate

Talc

Filtering agent

Use of talc because of its absorptive properties

Antiadherent

Use of talc because of its non absorptive properties

Lavosier

1st true periodic table

Dobereiner

Arrange elements by TRIADS

Newlands

Arrange elements by OCTAVES

Meyer and Mendeleev

Arrange elements by ATOMIC WEIGHT

Moseley

Arrange elements by ATOMIC NUMBER

1A

Alkali metals

2A

Alkaline earth metals

3A

Boron group

4A

Carbon group

5A

Nitrogen group

6A

Oxygen group

7A

Halogens

8A

Noble gases

Nitrogen group

Pnictogens

Carbon group

Crystallogens

Boron group

Icosagens

Oxygen group

Chalcogens

Cathode

Attract (+) ions

Anode

Attract (-) ions

Na

Major extracellular cation

K

Major intracellular cation

Cl

Major extracellular anion

NaHCO3

Important in neutralizing blood ph

Acidosis

Ph less than 7.35

Alkalosis

Ph more than 7.45

Acidosis

May lead to CNS depression

Alkalosis

May lead to CNS stimulation

Alkalosis

What happens intracellularly when there is an intracellular shift of K

Acidosis

What happens extracellularly when there is an intracellular shift of K

Acidosis

What happens intracellularly when there is an extracellular shift of K

Alkalosis

What happens extracellularly when there is an extracellular shift of K

Ionic bond

Bond between a metal and a non metal

Covalent bond

Bond between a non metal and a non metal

H N F O I C Br

Diatomic elements

I F O N S Cl Br

Highly electronegative elements

London

Non-Polar to Non-Polar

Keesom

Polar to Polar

Debeye

Polar to Non-Polar

Induced dipole Induced dipole

London

Dipole Dipole

Keesom

Dipole Induced dipole

Debeye

Arrhenius

Acids yield H+ in aq. soln

Arrhenius

Bases yield OH- in aq. soln

Bronsted-Lowry

Acids are proton donors

Bronsted-Lowry

Bases are proton acceptors

Lewis

Acids are electron acceptors

Lewis

Bases are electron donors

Arrhenius

Aka Water Theory of Acids and Bases

SA + SB

Neutral salt

SA + WB

Acidic salt

WA + SB

Basic salt

Hydroxides of group 1A and 2A

Strong bases

HCl
HBr
HNO3
HI
HClO4
H2SO4

Strong acids

Autoprotolysis

Aka self-ionization

Autoprotolysis

Transfer of protons bet. two identical molecules

Autocatalytic

When the reactant in a chem rxn is also the catalyst

Cu + Zn

Brass

Cu + Sn

Bronze

Hg + Ag + Sn + Cu

Amalgam

Fe + C + Si

Cast Iron

Fe + C

Steel

Au + Ag + Cu

Green gold

Cu + Al + Zn

Nordic gold

Mg + Al

Magnalium

Cu + Ni

Cupronickel

Ni + Cr

Nichrome

Ni + Ti

Nitinol