Chapter 16 Forensic Aspects of Fire and Explosion Investigation

energy

_____ is the capacity for doing work

chemical; mechanical

burning methane for the purpose of heating water to produce steam in order to drive a turbine is an example of converting _______ energy to ______ energy

ignition

the minimum temperature at which a fuel burns is known as the ____ temperature

pyrolysis

______ is the chemical breakdown of a solid material to gaseous products

glowing combustion

______ is a phenomenon in which a fuel burns without the presence of a flame

increases

the rate of a chemical reaction _____ as the temperature rises

spontaneous combustion

_____ describes a fire caused by a natural heat-producing process

origin

a search of the fire scene must focus on finding the fire's _____

porous

the collection of debris at the origin of a fire should include all _____ materials

airtight

______ containers must be used to package all materials suspected of containing hydrocarbon residues

gas chromatograph

the most sensitive and reliable instrument for detecting and characterizing flammable residues is the _____

pattern

the identity of a volatile petroleum residue is determined by the _____ of its gas chromatogram

cannot

the criminalist ____ identify gasoline residues by brand name

explosion

rapid combustion accompanied by the creation of large volumes of gases describes an _____

low

explosives that decompose at relatively slow rates are classified as ____ explosives

deflagration

the speed at which low explosives decompose is called the speed of _____

potassium nitrate, charcoal, and sulfur

three ingredients of black powder are ____, _____, and _____

high

______ explosives detonate almost instantaneously to produce a smashing or shattering effect

black powder; smokeless powder

the most widely used low explosives are _____ and _____

confined

a low explosive becomes explosive and lethal only when it is _____

primary; secondary

high explosives can be classified as either _____ or _____ explosives

RDX

the most widely used explosive in the military is _____

PETN

the explosive core in detonating cord is ____

Initiating

a high explosive is normally detonated by a ____ explosive contained within a blasting cap

Crater

an obvious characteristic of a high explosive is the presence of a ____ at the origin of the blast

~ Investigators recovered McVeigh's fingerprints from a receipt for 2,000 lbs of ammonium nitrate.
~ there was PETN (a component of detonating cord) residue on the clothing McVeigh wore the day of his arrest

Oklahoma City Bombing

~U.S. and Britain security agencies discovered a plot to destroy 10 planes with about a dozen liquid explosives
~ highlighted a type of liquid explosive based on peroxide.
~ The most comon peroxide explosive is TATP (can be detonator or primary explosive)

Liquid Explosives Case

Airtight Containers

All materials collected at a bombing site must be placed in an ___________ _________________ such as clean paint cans.

Ion Mobility Spectromemeter

A device widely used to screen objects for the presence of explosive residue is the ____________________

unconsumed explosive particles

Debris collected at explosion scenes is examined microscopically for ____________________.

color spot test; thin-layer chromatography; gas chromatography; mass spectometry

Recovered debris may be thoroughly rinsed with organic solvents and analyzed by testing procedures that include __________________, ___________________, _________________, ________________.

Infrared Spectrophotometry

Unconsumed explosives are identified by ___________________________.

Tetryl - Alcoholic KOH
TNT - Alcoholic KOH
Chlorate - Diphenylamin
Nitrocellulose -Diphenylamine

Which color test(s) would you use for each sample?
Tetryl
TNT
Chlorate
Nitrocellulose