Aveda Chapter 7

Chemistry

Scientific study of matter, the physical and chemical changes affecting matter and the energy changes that accompany those processes

Chemists

Scientists who study matter, its properties and changes

Biochemistry

The study of chemical reactions, such as growth, reproduction and respiration, that occur within a living organism

Organic chemistry

Deals with all matter that is now living or was alive at one time
Study of matter containing carbon

Inorganic chemistry

Deals with matter that was never living and does not contain carbon

Matter

Anything that occupies space

Solid

definite weight, volume, shape
Ex: rock

Liquid

Definite weight and volume, no shape
Ex: water

Gas

Definite weight, indefinite volume and shape
Ex: air

Physical change

a change in the physical form or properties of a substance that occurs without a change in composition
Ex: when water freezes and becomes ice

Chemical change

Change in substance that creates a new substance with different material characteristics from those of the original substance
Ex: when hydrogen and oxygen combine to create water

Sublimation

Solid passing into gaseous state without melting

Energy

Ability to do work or accomplish some change

Elements

Basic units of matter that cannot be broken down into simpler substances by any chemical reaction
Pure substances

Naturally occurring elements in nature

92

Periodic law

Used to organize elements and their similarities

Who came up with the periodic table

Dmitri Mendeleev, Lothar Meyer

Atomic number

Number shown in the table with each element
Indicates how many protons

Elements of interest for estheticians

Carbon, oxygen, hydrogen, nitrogen, sulfur

Atoms

Smallest complete unit of an element

Protons

Positively charged particles

Neutrons

No/neutral charge

Electrons

Negatively charged particles
Enable atoms to unite with other atoms to form bonds

molecular weight (MW)

Neutrons and protons together

Nucleus

Protons and neutrons tightly packed to form dense core at the center of an atom

Energy level

Electrons move around the nucleus at speed of light on orbiting paths

Reactivity of an atom depends on

Number of electrons present in the outermost shell

Free electron

The name given to an electron in the outermost orbit that is easily moved from its orbit. If another atom has a shortage of electrons, the free electron will attempt to move to it

Unstable atoms are

reactive

atoms not missing electrons are

stable

Molecules

When unstable atoms combine chemically by sharing electrons

Compounds

Created chemically by combining 2 elements

Chemical reaction

Reactions that occur on the outer shell of atoms
2 or more chemicals mixed together

Oxidation

Loses electron, oxygen required

Reduction

Gains electron, oxygen released

Ions

Charged atoms involved in chemical reaction

ionic bond

When positive and negative ions join

Covalent bond

If no trading is taking place and atoms are sharing electrons

Chemical bonds

forces that hold atoms together in compounds

3 major biochemical compound groups:

proteins, carbohydrates, lipids

Proteins

Help body construct and renew itself

Enzymes

Dissolve and break down large molecules into smaller ones

Amino acid

Compounds consisting of carbon, hydrogen, oxygen, nitrogen
Join to form peptide bond, polypeptide chain

Peptide bond

Bond uniting two amino acid groups

Polypeptide chain

Thousands of amino acids connected lengthwise to form a chain

Monomers

Basic building-block molecules that connect with each other to form larger, more complex compounds

Polymers

Groups of monomers that bond together

Carbohydrates

Store energy and play key role in metabolism

saccharide

A simple unit of a carbohydrate

Monosaccharide

Single saccharide, simple sugar
Ex: glucose

Disaccharide

2 saccharides together
Ex: sucrose

Polysaccharide

Many saccharides
Ex: starch

Lipids

Fill intercellular spaces in skin
Carbo, hydrogen, oxygen

pH (potential hydrogen)

Unit of measurement that indicates whether a substance is acidic, neutral or alkaline

Acid

More positive hydrogen ions than negative ions

Alkaline

More negative hydroxide ions
Base

Numbers below 7 on the pH scale

Acid

numbers above 7 on the pH scale

Alkaline

pH balanced

Balanced but not within range of 4.5-5.5

Acid balanced

Balanced within the acid range of 4.5-5.5

Pure distilled water has a pH of:

7

Hard water contains

calcium and magnesium

Soft water contains

Very few minerals

Mixture

2 or more substances physically combined rather than chemically

Solution

Mixture of 2+ chemicals in which each component is evenly dispersed in the mixture to form a complete homogenous dispersion

Solvent

Liquid part of solution

Solute

Solid or dissolved part of solution

Universal solvent

water

Miscible solvent

Solvents that easily mix together

Immiscible solvent

Solvents that don't mix easily with each other
Ex: oil, water

Suspension

Even dispersion of a solid substance in a liquid base
Ex: foundation

Gel

Formulated with a thickening agent to increase viscosity

Powder

finely ground solid mixed evenly with additional ingredients

Ointment

Anhydrous (without water) substance based on a mixture of oils and waxes normally having the texture of a paste

Stick

A hard, low-level water or anhydrous product applied to the skin by rubbing the product directly on the desired area
Ex: deodorant, lip balm

Aerosol

A product packaged under pressure and blended with a propellant (gas) inside a container, which is usually a can
Ex: hairspray

Emulsion

Mixture of 2+ nonmixable substances, United by small droplets of a binder (emulsifier)

Emulsifier

Binding substances used to slow down the destruction of the product

Viscosity

Thickness of a product

Creme and lotion

Emulsions used to impart emolliency and moisturization to the skin
Ex: sunscreen, lotion

Active ingredients

Responsible for producing the desired effect

International nomenclature for cosmetic ingredients INCI

Labeling is assigned using this

Most products are at least half

Water

Humectants

Organic ingredients that bind water and deposit it onto the skin
Normally found after water on ingredient list

Emollient

Condition and soften skin by providing protective lipid coating

Occlusive barrier

Created by Emollients and seal in moisture
Ex: wax

Fatty acids

lubricant ingredients derived from plant oils or animal fats
Used in cosmetic products to keep firm yet soft and easy to apply

Fatty alcohols

Fatty acids that have been exposed to hydrogen
used to increase the thickness of cosmetic products and provide moisturizing properties

Surfactant

Used in cleanser type products
Ability to bind wide variety of organic and inorganic matter to water

Thickeners/Viscosity Modifier

ingredients that increase density in emulsions and gel-type products

Botanicals

natural or naturally derived ingredients extracted from plants
Provide various anti-inflammatory, antibacterial, anti-irritant, antioxidant or conditioning effects

Preservatives

maintain microbiological integrity or product quality

chelating agents

Ingredients added to a product to enhance the effectiveness of the preservative

Coloring agents

Vegetable, mineral or pigment dyes that are added to products to enhance the products appearance
Not used often� cause allergic reactions

Fragrance

Not listed in ingredients label
Cover undesirable odors

Hypoallergenic

less likely to cause allergies

Antibacterial

Destroy bacteria that can cause problems such as acne or other infections
Ex: benzoyl peroxide

pH adjusters

Acids or bases used to adjust the product pH level to a desired level

Comedogenicity

Tendency to clog

Comedogenic

Ingredient likely to block or clog pores and contribute to pimples

Noncomedogenic

Ingredients that will not clog pores or cause comedones.

Sunscreens

Active ingredients, and are considered drug products under FDA guidelines

Antioxidants

Prevent skin inflammation and damage due to free radicals

Free radicals

Chemically unstable molecules caused by environmental pollutants and UV exposure

Co-enzyme Q-10

Occurs naturally in human cells
Aids in production of cellular energy, circulation
Stimulates immune system
Provides anti aging effects

Silicones

Act as mesh like pattern of waterproof molecules over the skin allowing oxygen molecules to penetrate, but keeping water inside

Hydroxy Acids

Organic acids extracted from a variety of natural sources including fruits, sugar, and milk
Speed up natural exfoliation process
Alpha, beta, poly

Alpha hydroxy acids (AHAs)

Carboxyl group located on the first carbon atom of the organic acid chain
Ex: glycolic, lactic acid

Beta hydroxy acids (BHAs)

Carboxyl group located on the second carbon atom of the organic acid chain
Ex: salicylic acid

Poly Hydroxy Acid (PHA)

Contain several carboxyl groups in the same chain
Ex: magic acid

Enzymes

Dissolve keratin proteins on surface of skin
Softer, smoother skin

Kinetin

an essential growth factor that prevents premature aging
Partially reverse clinical signs of photo damaged facial skin

Vitamins

Deliver variety of benefits to the skin

Lighteners

Used in skin treatment products in order to bleach or lighten areas of hyperpigmentation
Blocks production of melanin

regulation of cosmetic products

FFDCA, FPLA

Government authority responsible for regulating cosmetics

FDA