Chemistry Chapter 5 Vocab

electromagnetic radiation

a form of energy exhibiting wavelike behavior as it travels through space

wavelength

the shortest difference between equivalent points on a continuous wave

frequency

the number of waves that pass a given point per second

amplitude

the height of a wave from the origin to a crest, or from the origin to the trough

electromagnetic spectrum

includes all forms of electromagnetic radiation which vary in their frequencies and wavelength

quantum

the minimum amount of energy that can be gained or lost by an electron

Planck's constant

constant number in Joules times seconds

photoelectric effect

a phenomenon in which photoelectrons are emitted from a metal's surface when light of a certain frequency shines on the surface

photon

a particle of electromagnetic radiation with no mass that carries a quantum of energy

atomic emission spectrum

a set of frequencies of electromagnetic waves given off by atoms of an element; consists of a series of fine lines of individual colors

ground state

the lowest allowable energy state of an atom

quantum number

the number assigned to each orbit of an electron

de Broglie equation

predicts that all moving particles have wave characteristics and relates each particle's wavelength to its frequency, its mass, and Planck's constant

Heisenberg uncertainty principle

states that it is not possible to know precisely both the velocity and the position of a particle at the same time

quantum mechanical model of the atom

an atomic model in which electrons are treated as waves; also called the wave mechanical model of the atom

atomic orbital

a three-dimensional region around the nucleus of an atom that describes an electron's probable location

principle quantum number

assigned by the quantum mechanical model to indicate the relative sizes and energies of atomic orbitals

principle energy level

the major energy levels of an atom

energy sublevels

the energy levels contained within a principle energy level

electron configuration

the arrangement of electrons in an atom, which is prescribed by three rules--the aufbau principle, the Pauli exclusion principle, and Hund's rule

aufbau principle

states that each electron occupies the lowest energy orbit available

Pauli exclusion principle

states that a maximum of two electrons can occupy a single atomic orbital but only if the electrons have opposite spins

Hund's rule

states that single electrons with the same spin must occupy each equal-energy orbital before additional electrons with opposite spins can occupy the same orbitals

electron-dot structure

consists of an element's symbol, representing the atomic nucleus and inner-level electrons, that is surrounded by dots, representing the atom's valence electrons

s" orbital

sphere shaped

p" orbital

figure eight shaped

d" orbital

clover shaped

f" orbital

daisy shaped