Chemistry: A Molecular Approach 2nd Edition - Chapter 2: Atoms and Elements

law of conservation of mass

law stating energy is neither created nor destroyed in chemical reaction

law of definite proportions

law stating all samples of given compound have same proportions of constituent elements

law of multiple proportions

law stating that when 2 elements (A and B) from 2 different compounds, masses of element B that combine w/ 1g of element of A can be expressed as a ratio of smaller whole #s

atomic theory

theory that each element is composed of tiny indestructible particles called atoms; all atoms of a given element have same mass and other properties; atoms combine in simple, whole # ratios to form compounds

cathode rays

electrode in an electrochemical cell where reduction occurs; electrons flow toward cathode

cathode ray tube

stream of electrons produced when a high electrical voltage is applied between 2 electrodes within a partially evacuated

electrical charge

fundamental property of certain particles that causes them to experience force in presence of electric fields

electron

negatively charges, low mass particle on outside of nucleus of all atoms that occupies most of atom's volume but contributes almost none of its mass

radioactivity

state of those unstable atoms that emit subatomic particles or high-energy electromagnetic radiation

nuclear theory

theory that most of atom's mass and all positive charge is contributed in small, dense nucleus

nucleus

very small, dense core of atom that contains most of atom's mass and all of positive charge; composed of protons and neutrons

protons

positively charged subatomic particle found in nucleus of an atom

neutrons

electrically neutral subatomic particle found in nucleus of an atom, w/ mass almost equal to that of proton

atomic mass unit (amu)

unit used to express masses of atoms and molecule particles, defined as 1/12 mass of carbon atom containing 6 protons and 6 neutrons

atomic number

# of protons in an atom; defines element

chemical symbol

1 or 2 letter abbreviation for element listed directly below atomic # on periodic table

isotopes

atoms of some element w/ same # of protons but different # of neutrons and consequently different masses

natural abundance

relative % of particular isotope in naturally occurring sample w/ respect to other isotopes of same element

mass number

sum of # of protons and neutrons in an atom

ions

atom or molecule w/ net charge caused by loss or gain of electrons

cations

positively charged ions

anions

negatively charged ions

periodic law

law based on observation that when elements are arranged in order of increasing mass, certain sets of properties recur periodically

metals

large class of elements that are generally good conductors of heat and electricity, malleable, ductile, lustrous and tend to lose electrons during chemical changes

nonmetals

class of elements, tend to be poor conductors of heat and electricity and usually gain electrons during chemical reactions

metalloids

category of elements found on boundary between metals and nonmetals of periodic table, w/ properties intermediate between those of both groups; semimetals

semiconductors

material w/ intermediate electrical conductivity that can be changed and controlled

main-group elements

elements found in s or p blocks of the periodic table whose properties tend to be predictable based on position in table

transition metals/elements

elements in d block of periodic table whose properties tend to be less predictable based simply on position in table

family/group

columns within main group elements in periodic table that contain elements that exhibit similar chemical properties

noble gases

group 8a elements, largely nonreactive (inert) due to their stable filled p orbitals

alkali metals

highly reactive metals in group 1a of periodic table

alkaline earth metals

fairly reactive metals in group 2a of periodic table

halogens

highly reactive nonmetals in group 7a of periodic table

atomic mass

average mass in amu of atoms of a particular element based on relative abundance of various isotopes; numerically equivalent to mass in grams of 1 mole of element

mass spectrometry

experimental method of determining precise mass and relative abundance of isotopes in given sample using instrument called mass spectrometer

mole

a unit defined as the amount of material containing 6.0221421 * 10�� particles

Avogadro's number

# of ��C atoms in nexactly 12g of ��C; equal to 6.0221421 * 10��

molar mass

mass in grams of 1 mole of atoms of element; numerically equivalent to atomic mass of element in amu