Organic Test 3 General Review

Aldehyde

Ketone

Carbonyl Group

Alkane

Alkene

Alkyne

Alcohol

Methyl

CH?-

Ethyl

CH?-CH?-

Propyl

Isopropyl

Phenyl

Phenol

Benzene

Cyclohexane

Cyclohexene

Toluene

Aniline

...

Benzaldehyde

Acetophenone

-al

Ending used for an aldehyde

-one

Ending used for a ketone

-ol

Ending used for an alcohol

-yne

Ending used for an alkyne

-ene

Ending used for an alkene

-ane

Ending used for an alkane

Dec-

Prefix used for a 10 carbon chain

Non-

Prefix used for a 9 carbon chain

Oct-

Prefix used for an 8 carbon chain

Hept-

Prefix used for a 7 carbon chain

Hex-

Prefix used for a 6 carbon chain

Pent-

Prefix used for a 5 carbon chain

But-

Prefix used for a 4 carbon chain

Prop-

Prefix used for a 3 carbon chain

Eth-

Prefix used for a 2 carbon chain

Meth-

Prefix used for a 1 carbon chain

Conditions for Hydrogenation

H? and Ni, Pd, or Pt catalyst

Conditions for Hydration

H?O and acid (H?) catalyst

Conditions for Oxidation

[O]

Conditions for Dehydration

H?SO? and heat

Conditions for Reduction

H? and Ni, Pd, or Pt catalyst

2 Steps of Hydrogenation

1. One H bonds to each Double Bonded C
2. Remove Double Bond

2 Steps for Hydration

1. The -H and -OH bond to either Double Bonded C
2. Remove Double Bond

2 Steps for Oxidation

1. Remove -H from -OH group and -H from C to form H?O
2. Form the Double Bond between C and O.

2 Steps for Dehydration

1. Remove an -H and -OH on adjacent C's to form H?O
2. Form a Double Bond Between these adjacent C's

2 Steps of Hemiacetal Formation

1. Break C=O Double Bond of aldehyde or ketone
2. Add-H of alcohol to O; Add -OR of alcohol to C

2 Steps of Acetal Formation

1. Add -H of alcohol to -OH of hemiacetal, which leaves as H?O
2. Add -OR of alcohol to C of hemiacetal

Cis

Trans

Reactant for Hydrogenation

Alkene

Product of Hydrogenation

Alkane

Reactant for Hydration

Alkene

Product of Hydration

Alcohol

Reactant of Oxidation

1� alcohol, 2� alcohol, or aldehyde

Product of Oxidation of 1� alcohol

Aldehyde

Product of Oxidation of 2� alcohol

Ketone

Product of Oxidation of 3� alcohol

No Reaction

Product of Oxidation of Aldehyde

Carboxylic Acid

Product of Oxidation of Ketone

No Reaction

Reactants of Hemiactetal formation

Aldehyde or Ketone and Alcohol

Reactants of Acetal formation

Hemiacetal and Alcohol